What should I do of the stuff? All of them
After reviewing the graph you have given with the question, there are several reasons why carbon 14 can't be used to accurately determine the age of organic remains that are 1 million years old.
A few of the reasons are; Carbon-14 has a short half life, after 1,000,000 years there wouldn't be enough carbon 14, and too little of the original radioactive sample would remain. Any of these choices are correct for the answer to the question you asked.
The earliest of civilizations were based around river valleys. This allowed them to irrigate fresh water to their crops allowing for better farming and therefore, bigger and better civilizations.
Iron Curtain is the best answer. Hope this helps you!