D. parallel structure just means that all of your verbs in the comma series line up in regards to tenses, here. in choice D, it's "BE friendly," "INTRODUCE yourself," and "SMILE." these are all present tense verbs.
the rest of the choices don't match--"exercise" and "stretching" are two different verb forms in choice A, "to go to the library" is the odd one out in choice B, ane "to build" doesn't match with the "-ing" verbs in choice C.
Yes, technically speaking this sentence is properly punctuated, although it should be noted that this is somewhat a matter of style, since there could be a period where the semi-colon is.
