In the suggest period between 200,000 and 12,000 years ago, humans were living a nomadic lifestyle. The humans of this period were hunter-gatherers, and they were constantly moving from one place to another in accordance to the food supply and climate conditions. Because of this constant movement and constant search for better hunting grounds and places where there's much bigger and more constant supply of fruits, vegetables, root plants, they managed to disperse in very big space and little by little to colonize the planet. In this period the cultivation of plants was still not taking place, and also the humans still hadn't managed to domesticate any wild animals, apart from the wolf which gave rise to the dog, but it was used for hunting, not as a food source.
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Yes, the data from mass spectrometry has helped modern scientists to make modifications to Dalton's model.
Dalton's model consisted of a single atom and that basically the atom is the smallest object. At the time, no discovered what are inside of atoms.
Atoms are made up of small particles, protons, neutrons and electrons. A mass spectrometer is an instrument that is able to see what is inside an atom. With this item, scientists have proved that atoms are not the smallest in the world cause the objects in them are smaller.