Syncopation is the accenting of a note which would usually not be accented. Syncopation is often described as being off beat. The time signature of a piece of music gives an indication of a regular pattern of strong and weak beats. A syncopated rhythm goes against this pattern by putting the accent on weak beats.
Good design is possible without understanding the principles of design. But it may take a lot of trial and error to create something that both looks good and creates an optimal user experience.