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Olenka [21]
4 years ago
12

As shown in the figure below, EBT solution is blue when pH is adjusted to 10. When calcium chloride is added to EBT solution, th

e color turns red due to the formation of EBT-metal complex. If you use your standard EDTA solution to titrate/quantify a calcium chloride (CaCl2) solution with unknown concentration, what is the color of the solution at end point?
Chemistry
1 answer:
inna [77]4 years ago
3 0

Answer:

The color of solution at the end point will be blue.

Explanation:

EBT is used as an indicator for complexometric titrations and acts as a chelating agent. It has a blue color, in its free form, when the pH is adjusted to 10.

On the addition of CaCl₂, EBT binds with Ca(II) and gives a red color, due to its EBT-Ca (II) complex. So, the color at the start of the titration is red.

When EDTA is added, it starts to form EDTA-Ca(II) complex. Near the endpoint, it starts to replace EBT bound to Ca, because it has a higher formation constant (Kf) for its EDTA-Ca(II) complex than EBT-Ca(II) complex. The EDTA-Ca(II) has no color so the solution shows the colour of free EBT, which is blue. Hence the color at the endpoint will be blue.

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