The statement that describes the 3d, 4s, and 4p orbitals of arsenic (as) based on its electronic configuration and position in the periodic table is; The 3d and 4s orbitals are completely filled, and the 4p orbital is partially filled.
The electronic configuration of arsenic is given as; 1s² 2s² 2p^(6) 3s² 3p^(6) 4s² 3d^(10) 4p³.
Now we can see that in that electronic configuration the orbitals are, s, p and D.
Now, the maximum electrons for each of the 3 orbitals are;
Maximum electrons for d orbital = 10 electrons
Maximum electrons for s orbital = 2 electrons
Maximum electrons for p orbital = 6 electrons.
Now, when we compare the maximum number of electrons for each orbital to the ones in electron configuration of arsenic, it is clear from the last 3 orbitals that the 3d and 4s orbitals are completely filled while the 4p orbital is half filled or partially filled.
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It can lead to deadly changes.
The calculated pH of the solutions are given below:
- The pH of the solution after 14.0 ml of base is added to it is calculated as 1.45.
- The pH of the solution after 19.8 ml of base is added to it is calculated as 3.0
- The pH of the solution after 20.0 ml of base is added to it is calculated as 7.
<h3>What is pH?</h3>
This is the level of acidity or alkalinity of an aqueous solution. The pH of a substances tells if its an acid, base or neutral.
HBr and NaOH while in water would dissociate and they would become H+ and OH- respectively.
Mol of HBr = Mol * Vol
= 0.200 * 20mL
= 4 mmol
A. Moles of NaOH added
= 0.2 X 14
= 2.8 mmol
Moles of H+ that did not react
= 4 - 2.8
= 1.2 mmol
1.2/1000 = 0.0012 moles
Total volume = 20 + 14
= 34 mL to litres
= 0.034 L
Molarity of H+ = 0.0012 / 0.034L
= 0.035 M
-log[0.035] = 1.45
The pH of the solution is 1.45
B. NaOH added = 19.8 * 0.2 =
3.96 mmoles
The unreacted solution
= 4.0 - 3.96
= 0.04 mmol
0.04/1000 = 0.00004 moles
Total volume = 20 + 19.8
= 39.8mL
Converted to litres = 0.0398L
Molarity = 0.00004 / 0.0398L
= 0.001
-log(0.001) = 3.0
The ph Is therefore 3.0
C. Moles of NaOH added = 0.2*20mL = 4mmol
All the H+ are going to be consumed here. This would result into a neutral solution pH = 7
<u>Complete question:</u>
20.0 mL sample of 0.200 M HBr solution is titrated with 0.200 M NaOH solution. Calculate the PH of the solution after the following volumes of base have been added.
A. 14.0 mL
B. 19.8 mL
C. 20.0 mL
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