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Alla [95]
4 years ago
6

Glycerol (C3H8O3), also called glycerine, is widely used in the food and pharmaceutical industries. Glycerol is polar and dissol

ves readily in water and polar organic solvents like ethanol. Calculate the mole fraction of the solvent in a solution that contains 1.61 g glycerol dissolved in 22.60 mL ethanol (CH3CH2OH; density?
Chemistry
1 answer:
Stells [14]4 years ago
7 0

Here is the complete question.

Glycerol (C3H8O3), also called glycerine, is widely used in the food and pharmaceutical industries. Glycerol is polar and dissolves readily in water and polar organic solvents like ethanol. Calculate the mole fraction of the solvent in a solution that contains 1.61 g glycerol dissolved in 22.60 mL ethanol (CH3CH2OH; density = 0.7893 g/mol). Round to four significant digits

Answer:

0.9567 mol

Explanation:

Given that:

mass of glycerol = 1.61 g

molar mass of glycerol = 92.1 g/mol

no of mole = \frac{mass}{molar mass}

∴ number of moles of glycerol (n_{glycerol}) = \frac{1.61}{92.1}

= 0.0175 mol

Volume of ethanol = 22.60 mL

Density of ethanol = 0.7893 g/mL

Since Density = \frac{mass}{volume}

∴  mass of ethanol = density of ethanol × volume of ethanol

mass of ethanol =  0.7893 g/mL × 22.60 mL

mass of ethanol =  17.838 g

Number of moles of ethanol (n_{ethanol}) = \frac{17.838}{46.0684}

= 0.387 mole

∴ the mole fraction of the solvent can be determined as:

X_{solvent} = X_{ethanol} = \frac{n_{ethanol}}{n_{glycerol}+n_{ethanol}}

=\frac{0.387 mol}{(0.0175+0.387)mol}

= \frac{0.387mol}{0.4045mol}

= 0.95673671199

≅ 0.9567 mol

∴ The mole fraction of the solvent in a solution that contains 1.61 g glycerol dissolved in 22.60 mL ethanol is = 0.9567 mol

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ELECTROLYSIS OF MOLTEN NaCl IS DONE IN A DOWNS CELL OPERATING AT 7.0 VOLTS AND 4.0X10^4A. HOW MUCH Na(s) AND Cl2(g) CAN BE PRODU
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Answer:

Mass of sodium produced = 2.74 × 10⁵ g of Na

Mass of chlorine produce = 4.24 × 10⁵ g of Cl₂

Explanation:

In the electrolysis of molten NaCl as described above, the quantity of charge used is given by the formula, Q = I × t

Where I isnthe current passed in amperes and t is time in seconds.

Q = 4.0 × 10⁴ A × (8 × 60 × 60) s = 1.152 × 10⁹ C

Equation for the discharge of sodium is; Na+ + e- ---> Na (s)

One mole of electrons is required to discharge one mole of Na

One mole of electron = 1 faraday = 96500 C

One mole of Na has a mass of 23 g

96500 C produces 23 g of Na

1.152 × 10⁹ C will produce 23 g × 1.152 × 10⁹ C / 96500 C = 2.74 × 10⁵ g of Na

Equation for the discharge of chlorine gas is; 2 Cl- ---> Cl₂(g) + 2e-

Two mole of electrons are required to discharge one mole of chlorine gas

Two moles of electron = 2 faraday = 2 × 96500 C = 193000

One mole of Cl₂ has a mass of 71 g

193000 C produces 71 g of Cl₂

1.152 × 10⁹ C will produce 71 g × 1.152 × 10⁹ C / 193000 C = 4.24 × 10⁵ g of Cl₂

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3 years ago
Aluminum chloride can be formed from its elements:
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<u>Answer:</u> The \Deltas H^o_{formation} for the reaction is -1406.8 kJ.

<u>Explanation:</u>

Hess’s law of constant heat summation states that the amount of heat absorbed or evolved in a given chemical equation remains the same whether the process occurs in one step or several steps.

According to this law, the chemical equation is treated as ordinary algebraic expressions and can be added or subtracted to yield the required equation. This means that the enthalpy change of the overall reaction is equal to the sum of the enthalpy changes of the intermediate reactions.

The chemical reaction for the formation reaction of AlCl_3 is:

2Al(s)+3Cl_2(g)\rightarrow 2AlCl_3 (s)    \Delta H^o_{formation}=?

The intermediate balanced chemical reaction are:

(1) HCl(g)\rightarrow HCl(aq.)    \Delta H_1=-74.8kJ    ( ×  6)

(2) H_2(g)+Cl_2(g)\rightarrow 2HCl(g)    \Delta H_2=-185kJ     ( ×  3)

(3) AlCl_3(aq.)\rightarrow AlCl_3(s)    \Delta H_3=+323kJ     ( ×  2)

(4) 2Al(s)+6HCl(aq.)\rightarrow 2AlCl_3(aq.)+3H_2(g)    \Delta H_4=-1049kJ

The expression for enthalpy of formation of AlCl_3 is,

\Delta H^o_{formation}=[6\times \Delta H_1]+[3\times \Delta H_2]+[2\times \Delta H_3]+[1\times \Delta H_4]

Putting values in above equation, we get:

\Delta H^o_{formation}=[(-74.8\times 6)+(-185\times 3)+(323\times 2)+(-1049\times 1)]=-1406.8kJ

Hence, the \Deltas H^o_{formation} for the reaction is -1406.8 kJ.

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Answer: 3.59

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3.59058 to 3 significant figures:

First three digits = 3.59

Fourth digit '0' is less than 5, and thus rounded to 0 with other succeeding digits

Therefore, (2.06)(1.743)(1.00) to 3 significant figures equals :

3.59

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