The prepositions in the sentence given in the question are: of, in.
What is preposition?
Adpositions, a class of terms that also includes prepositions and postpositions, are employed to denote a variety of semantic duties as well as to denote spatial or temporal links. A preposition or postposition's complement, or occasionally object, is the noun phrase it usually joins. The links between direction, time, place, location, and space can also be indicated with prepositions. Prepositions are used to introduce an object before a noun, pronoun, or noun phrase, to put it another way. In order to establish a connection between a noun or pronoun and the other components of the phrase, prepositions are typically used before a noun or pronoun. Examples of prepositions are "in," "at," "on," "of," and "to."
The sentence here is "Although he weighed only 175 pounds, Clemente used one of the heaviest bats in the big leagues." here the word in and of are establishing connection that's why they are considered as prepositions.
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