I believe the answer u are looking for is the third one. The first one makes no sense, the second one's comma is in middle of a description, so no. The las one is just the combine of 1&2. So 3 is right
<span>Ricardo screamed as he spilled his frozen pineapple slushy.
It is unnatural to put the comma after a verb, so that rules out the first and fourth options. A comma goes between two adjectives when they mean similar things. For example, <em>big, fat dog</em> is correct, but not <em>big fat dog</em> <em> </em><em>Frozen, pineapple slushy. </em><em>Pineapple, frozen slushy.</em>
The second one does not make sense, so you can't use a comma. That rules out the second option.</span>