Function of an enzyme is to lower reaction's activation energy and to increase speed of a reaction, but to make it happen, enzyme and substrate must fit spatially. The shape of an enzyme is essential to make enzyme-substrate complex - if active site of an enzyme doesn't fit to substrate, there won't be a enzyme-catalised reaction.
Fixation converts nitrogen in the atmosphere into forms that plants can absorb through their root systems. A small amount of nitrogen can be fixed when lightning provides the energy needed for N