Answer: The pH of 0.10 M
is 4.49.
Explanation:
Given: Initial concentration of
= 0.10 M

Let us assume that amount of
dissociates is x. So, ICE table for dissociation of
is as follows.
![Cu(H_{2}O)^{2+}_{6} \rightleftharpoons [Cu(H_{2}O)_{5}(OH)]^{+} + H_{3}O^{+}](https://tex.z-dn.net/?f=Cu%28H_%7B2%7DO%29%5E%7B2%2B%7D_%7B6%7D%20%5Crightleftharpoons%20%5BCu%28H_%7B2%7DO%29_%7B5%7D%28OH%29%5D%5E%7B%2B%7D%20%2B%20H_%7B3%7DO%5E%7B%2B%7D)
Initial: 0.10 M 0 0
Change: -x +x +x
Equilibrium: (0.10 - x) M x x
As the value of
is very small. So, it is assumed that the compound will dissociate very less. Hence, x << 0.10 M.
And, (0.10 - x) will be approximately equal to 0.10 M.
The expression for
value is as follows.
![K_{a} = \frac{[Cu(H_{2}O)^{2+}_{6}][H_{3}O^{+}]}{[Cu(H_{2}O)^{2+}_{6}]}\\1.0 \times 10^{-8} = \frac{x \times x}{0.10}\\x = 3.2 \times 10^{-5}](https://tex.z-dn.net/?f=K_%7Ba%7D%20%3D%20%5Cfrac%7B%5BCu%28H_%7B2%7DO%29%5E%7B2%2B%7D_%7B6%7D%5D%5BH_%7B3%7DO%5E%7B%2B%7D%5D%7D%7B%5BCu%28H_%7B2%7DO%29%5E%7B2%2B%7D_%7B6%7D%5D%7D%5C%5C1.0%20%5Ctimes%2010%5E%7B-8%7D%20%3D%20%5Cfrac%7Bx%20%5Ctimes%20x%7D%7B0.10%7D%5C%5Cx%20%3D%203.2%20%5Ctimes%2010%5E%7B-5%7D)
Hence, ![[H_{3}O^{+}] = 3.2 \times 10^{-5}](https://tex.z-dn.net/?f=%5BH_%7B3%7DO%5E%7B%2B%7D%5D%20%3D%203.2%20%5Ctimes%2010%5E%7B-5%7D)
Formula to calculate pH is as follows.
![pH = -log [H^{+}]](https://tex.z-dn.net/?f=pH%20%3D%20-log%20%5BH%5E%7B%2B%7D%5D)
Substitute the values into above formula as follows.
![pH = -log [H^{+}]\\= - log (3.2 \times 10^{-5})\\= 4.49](https://tex.z-dn.net/?f=pH%20%3D%20-log%20%5BH%5E%7B%2B%7D%5D%5C%5C%3D%20-%20log%20%283.2%20%5Ctimes%2010%5E%7B-5%7D%29%5C%5C%3D%204.49)
Thus, we can conclude that the pH of 0.10 M
is 4.49.
Answer:
to help children learn more about their ecosystem and to give more knowledge
Explanation:
because we need to learn new things
So the solution inside doesn't splash
Answer:
Br- Withdraws electrons inductively
Donates electrons by resonance
CH2CH3 - Donates electrons by hyperconjugation
NHCH3- Withdraws electrons inductively
Donates electrons by resonance
OCH3 - Withdraws electrons inductively
Donates electrons by resonance
+N(CH3)3 - Withdraws electrons inductively
Explanation:
A chemical moiety may withdraw or donate electrons by resonance or inductive effect.
Halogens are electronegative elements hence they withdraw electrons by inductive effect. However, they also contain lone pairs so the can donate electrons by resonance.
Alkyl groups donate electrons by hyperconjugation involving hydrogen atoms.
-NHCH3 and contain species that have lone pair of electrons which can be donated by resonance. Also, the nitrogen and oxygen atoms are very electron withdrawing making the carbon atom to have a -I inductive effect.
+N(CH3)3 have no lone pair and is strongly electron withdrawing by inductive effects.