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Ilia_Sergeevich [38]
3 years ago
15

Write down the equation for the Lewis-Randall rule for fugacity of species in an ideal solution.

Chemistry
1 answer:
mr_godi [17]3 years ago
7 0

Answer :

Lewis-Randall rule : Lewis-Randall rule states that, the fugacity of a component is directly proportional to the mole fraction of the component in the solution in an ideal solution.

The equation used for the Lewis-Randall rule for fugacity of species in an ideal solution is :

f_i=X_i\times f_i^o

where,

f_i = fugacity in the solution

f_i^o = fugacity of a pure component

X_1 = mole fraction of component

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But what happens when the two atoms involved in a bond aren’t the same? The two positively charged nuclei have different attractive forces; they “pull” on the electron pair to different degrees. The end result is that the electron pair is shifted toward one atom.

ATTRACTING ELECTRONS: ELECTRONEGATIVITIES

The larger the value of the electronegativity, the greater the atom’s strength to attract a bonding pair of electrons. The following figure shows the electronegativity values of the various elements below each element symbol on the periodic table. With a few exceptions, the electronegativities increase, from left to right, in a period, and decrease, from top to bottom, in a family.

Electronegativities give information about what will happen to the bonding pair of electrons when two atoms bond. A bond in which the electron pair is equally shared is called a nonpolar covalent bond. You have a nonpolar covalent bond anytime the two atoms involved in the bond are the same or anytime the difference in the electronegativities of the atoms involved in the bond is very small.



Now consider hydrogen chloride (HCl). Hydrogen has an electronegativity of 2.1, and chlorine has an electronegativity of 3.0. The electron pair that is bonding HCl together shifts toward the chlorine atom because it has a larger electronegativity value.

A bond in which the electron pair is shifted toward one atom is called a polar covalent bond. The atom that more strongly attracts the bonding electron pair is slightly more negative, while the other atom is slightly more positive. The larger the difference in the electronegativities, the more negative and positive the atoms become.

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. In a titration, a 25.0 mL sample of 0.150 M HCl is neutralized with 44.45 mL of Ba(OH)2. a. Write the balanced molecular equat
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Answer:

Equation of reaction:

a) 2HCl + Ba(OH)2 ==> CaCl2 + 2H2O

b) Molarity of base = 0.042 M.

Explanation:

Using titration equation

CAVA/CBVB = NA/NB

Where NA is the number of mole of acid = 2

NB is the number of mole of base = 1

CA is the molarity of acid =0.15M

CB is the molarity of base = to be calculated

VA is the volume of acid = 25 ml

VB is the volume of base = 44.45mL

Substituting

0.15×25/CB×44.45 = 2/1

Therefore CB =0.15×25×1/44.45×2

CB = 0.042 M.

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