The mechanisms of reproductive isolation prevent the reproduction of two individuals from different species. The prezygotic mechanisms disrupt the stages of reproduction before the forming of the zygote or prevent the mating at the start, and the postzygotic mechanisms affect the stages of reproduction after the forming of the zygote. So, the first and the third example (the urchins and the grasshoppers) show the prezygotic mechanism, as the two individuals are not able to mate or form a zygote. The second and the fourth example ( zonkey and the death of a zygote) show the working of the postzygotic mechanisms, as the zygote is formed, but it seems to be inviable, and the zonkeys are sterile, preventing the individual to reproduce.
Bioaccumulation is the process by which toxins enter the food web by building up in individual organisms, while biomagnification is the process by which toxins are passed from one trophic level to the next (and thereby increase in concentration) within a food web.
