In an 1H NMR spectrum, the signal for vinyl proton is generally more downfield than an alkyl proton because the additional magnetic field created by the π electrons causes the nearby protons to resonate at a higher frequency.
<h3>What is meant by NMR? </h3>
NMR stands for nuclear magnetic resonance. In this technique, various molecules are studied by studying the interactions of their nucleus with electromagnetic radiations and then recording their radiofrequency.
The nuclei in this case are placed in a strong magnetic field.
This effect was discovered by Zeeman. It is used to study the magnetic properties of nuclei of certain atoms so that they can be appropriately utilized.
Therefore, In a 1H NMR spectrum, the vinyl proton signal is more downfield than an alkyl proton because the additional magnetic field created by the π electrons causes the nearby protons to resonate at a higher frequency.
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The freezing water would sink to the bottom and freeze the lake water from the bottom up.
It's volume increases much more rapidly than it's surface area.
<span>Explanation: Oxygen is the more electro-negative of the atoms in the water molecule, so it tends to pull the 'shared' electron more to itself. Thus, the oxygen atom has a greater time-share of all electrons, and therefore the hydrogen atoms are more positive for a partial lack of electrons</span>
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