Basically. They had the biggest ego ever. The North knew that they had the more resources and the more superior military force. So they basically underestimated the South. Also it was due to the North's military generals. They didn't lead the troops the right way and all in all, that led to early Confederate victory. The South had the superior military leadership against the North.
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Like the Associate Justices, the Chief Justice is appointed by the President and confirmed by the Senate. There is no requirement that the Chief Justice serve as an Associate Justice, but 5 of the 17 Chief Justices have served on the Court as Associate Justices prior to becoming Chief Justice.
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