I would venture to say that the country in South America that has the least amount of disposable water would be probably in northern Chile which is a desert ie the Atacama desert which stretches from the Pacific across to the Andes Mts while on the other hand, in southern Chile there is a temperate climate with significant rainfall and considerable disposable water.
C. Atmosphere - which is the one sphere that means "air" or "gasses". The other ones mean, Biosphere = "living", Lithosphere = "land", and Hydrosphere = "water"