Rivers, mountain ranges, oceans, and deserts can all serve as physical boundaries. Many times, political boundaries between countries or states form along physical boundaries. For example, the boundary between France and Spain follows the peaks of the Pyrenees mountains, while the Alps separate France from Italy.
Political boundaries are the dividing lines between countries, states, provinces, counties, and cities. These lines, more often called borders, are created by people to separate areas governed by different groups. Sometimes, political boundaries follow physical boundaries, but most of the time you can't see them