Well, CEOs are on the top of the food chain. It takes a lot of work and ambition to become one, and once they are one, <span>CEOs accept a huge amount of responsibility - that means having to take blame if things go wrong and </span><span>having more tasks to complete such as having to attend numerous meetings, make decisions. They are also on the board of directors.</span>
Assistants do not have to do as much, they likely won't have that much responsibility or experience, their tasks revolve around ensuring meetings are scheduled and performing other ad-hoc duties.