Which of the following elements has properties different than the rest? K O H N
1 answer:
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i. The dissolution of PbSO₄ in water entails its ionizing into its constituent ions:
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ii. Given the dissolution of some substance
,
the Ksp, or the solubility product constant, of the preceding equation takes the general form
.
The concentrations of pure solids (like substance A) and liquids are excluded from the equilibrium expression.
So, given our dissociation equation in question i., our Ksp expression would be written as:
.
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iii. Presumably, what we're being asked for here is the <em>molar </em>solubility of PbSO4 (at the standard 25 °C, as Ksp is temperature dependent). We have all the information needed to calculate the molar solubility. Since the Ksp tells us the ratio of equilibrium concentrations of PbSO4 in solution, we can consider either [Pb2+] or [SO4^2-] as equivalent to our molar solubility (since the concentration of either ion is the extent to which solid PbSO4 will dissociate or dissolve in water).
We know that Ksp = [Pb2+][SO4^2-], and we are given the value of the Ksp of for PbSO4 as 1.3 × 10⁻⁸. Since the molar ratio between the two ions are the same, we can use an equivalent variable to represent both:
So, the molar solubility of PbSO4 is 1.1 × 10⁻⁴ mol/L. The answer is given to two significant figures since the Ksp is given to two significant figures.
Answer:
All bonds are equivalent in length and strength within the molecule.
Gaseous SO3 is a trigonal planar molecule that exhibit a D3h symmetry group.
Sulfur has sp2 hybridization and it has 6 outer electrons which make the bonds with the oxygen.
Its constituent sulfur atom has an oxidation state of +6 and a formal charge of 0.
The Lewis structure is made up of one S=O double bond and two S–O dative bonds that doesn't not engage the d-orbitals. ( Thus, SO3 molecule has three double bonded oxygen to the central sulfur atom). This explains the strength.
It gaseous form had a zero electrical dipole moment because of the 120° angle between the S-O bonds.
Explanation:
