Answer:
Option D. 4.02 kJ
Explanation:
A simple calorimetry problem
Q = m . C . ΔT
ΔT = Final T° - Initial T°
C = Specific heat capacity
m = mass
Let's replace the data
Q = 125 g . 2.42 J/g∘C . (34.8°C -21.5 °C)
Q= 4023.25 J
We must convert the answer to kJ
4023.25 J . 1kJ /1000 =4.02kJ
Here we assume that disintegration has occur so the normal t½ formular will not be used
mathematically we..⅛×5600 =700
therefore it is about 700years option A
Resonance, leaving group, carbonyl carbon delta+, and steric effect is the most crucial variables that affect the relative reactivity of a functional group containing a carbonyl in an addition or substitution process.
Discussion:
1. Carbonyl Carbon Delta+: The carbonyl group becomes more electrophilic and accelerates nucleophilic assault when the carbonyl carbon delta+ is bigger.
2. Resonance: When the carbonyl is transformed into the tetrahedral adduct, it may be lost. Loss of resonance increases the energy of the transition state for this nucleophilic assault because resonance has the function of stabilizing. Therefore, a carbonyl functional group's resistance to nucleophilic attack increases as resonance in the group increases in importance.
3. Leaving group: Tetrahedral adduct fragmentation is encouraged by a better LG.
4. Steric effects: The nucleophilic attack on carbonyl carbon is delayed when sterically impeded.
Learn more about carbonyl here:
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Answer is 0.1565417867........
