The answer to this question would be: (4)carnivoresFood made by autotrophs which makes them placed first in food webs as they produce food. After that, the herbivore can digest the food made by autotroph, makes them places as the first consumer. Carnivores is the organism that eats meat, makes them the last consumer.
Limestone is composed largely of the minerals calcite or aragonite. Some limestones do not consist of grains and are formed by the chemical precipitation of calcite or aragonite. This is how limestone can be classified as chemical.
Answer:
The first one
When pulling a tree from the ground