Yes, the data from mass spectrometry has helped modern scientists to make modifications to Dalton's model.
Dalton's model consisted of a single atom and that basically the atom is the smallest object. At the time, no discovered what are inside of atoms.
Atoms are made up of small particles, protons, neutrons and electrons. A mass spectrometer is an instrument that is able to see what is inside an atom. With this item, scientists have proved that atoms are not the smallest in the world cause the objects in them are smaller.
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The following paper draws on material originally contained in IMF Working Paper 97/42, "Deindustrialization: Causes and Implications," by Robert Rowthorn, Professor of Economics, Cambridge University, and Ramana Ramaswamy of the IMF’s Research Department. Neil Wilson prepared the present version. Readers interested in the original Working Paper may purchase a copy from IMF Publication Services