I am thinking the correct answer among the choices presented is option D. The sentence that does not properly use a subordinating conjunction is "He acts like he's going to cry". This is because it does not have any joining of clauses in the sentence.
"Throughout the years, numerous organizations offered aid to immigrants at Ellis Island."
that is the best one from the sentences you provided, hope it helps
They were promised to be awarded with their freedom in return for their services.
Fardels usually mean a group of stories