Prediction for the reactivity of a chlorine directly on the double bond of an alkene would be in the following:
A dipole is created in the halogen molecule as the non-polar chlorine molecule approaches the alkene double bond.
A chloride ion is produced when the pi link in the alkene double bond breaks and establishes a bond with the delta positive Cl atom.
The chloride ion undergoes carbocation as a result, and along with the carbocation, a single electron pair forms a dative bond.
Carbon double bonds are more powerful and compact than single bonds. The number of bonds is two.
Additionally, double bonds have a lot of electrons, which could make them more reactive in the presence of a powerful electron acceptor.
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