Answer : The oxidation state of nitrogen in
is, (+5)
Explanation :
Rules for the oxidation numbers :
- The oxidation number of a free element is always be zero.
- The oxidation number of a monatomic ion equal to the charge of the ion.
- The oxidation number of Hydrogen (H) is +1.
- The oxidation number of oxygen (O) in compounds is usually -2, but it is -1 in the peroxides.
- The oxidation number of a Group 1 element in a compound is +1.
- The oxidation number of a Group 2 element in a compound is +2.
- The oxidation number of a Group 17 element in a binary compound is -1.
- The sum of the oxidation numbers of all of the atoms in a neutral compound is zero.
- The sum of the oxidation numbers in a polyatomic ion is equal to the charge of the ion.
The given compound is,
Let the oxidation state of 'N' be, 'x'
Hence, the oxidation state of N is, (+5)
Answer : The heat of the reaction is, 1.27 kJ/mole
Explanation :
First we have to calculate the heat released.
Formula used :

or,

where,
Q = heat = ?
m = mass of sample = 1.50 g
c = specific heat of water = 
= initial temperature = 
= final temperature = 
Now put all the given value in the above formula, we get:


Now we have to calculate the heat of the reaction in kJ/mol.

where,
= enthalpy change = ?
Q = heat released = 0.0238 kJ
n = number of moles NH₄NO₃ = 

Therefore, the heat of the reaction is, 1.27 kJ/mole
Answer:
The correct answer is - 4-nitroaniline.
Explanation:
It is given that all three solid compounds salicylic acid + 4-nitroaniline + naphthalene are equal in the ratio in the mixture and then 1 gram of this mixture is dissolved in the diethyl ether and run a drop of the solution on TLC plate. This plate shows three spots.
The salicylic acid and naphthalene would stay dissolved in the diethyl ether solution due to the 4-nitroaniline could be extracted by adding aqueous acid and involve in the aqueous layer and thus spot of 4-nitroaniline would be with largest Rf value.