Question

Suppose you have a 1:1:1 by weight mixture of three solid compounds, salicylic acid 4-nitroaniline naphthalene. You dissolve 1 gram of this mixture in diethyl ether, and place a tiny drop of the ether solution on a TLC plate. After developing the TLC plate, you see three spots. Which compound would would you expect to have the largest Rf value

Answer 1

Answer:

The correct answer is - 4-nitroaniline.

Explanation:

It is given that all three solid compounds salicylic acid + 4-nitroaniline + naphthalene are equal in the ratio in the mixture and then 1 gram of this mixture is dissolved in the diethyl ether and run a drop of the solution on TLC plate. This plate shows three spots.

The salicylic acid and naphthalene would stay dissolved in the diethyl ether solution due to the 4-nitroaniline could be extracted by adding aqueous acid and involve in the aqueous layer and thus spot of 4-nitroaniline would be with largest Rf value.