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Svetlanka [38]
4 years ago
11

At 700 K, CCl4 decomposes to carbon and chlorine. The Kp value for the decomposition is 0.76. Find the starting pressure of CCl4

at this temperature that produces a total pressure of 1.9 atm at equilibrium.
Chemistry
1 answer:
Vladimir79 [104]4 years ago
6 0
The decomposition of CCl4 is as follows:

CCl4 (g) ---> C(s) + 2Cl2 (g)                 Kp = 0.76

where Kp = (PCl2)^2 / (P_CCl4)

P_C is zero since carbon is in solid form.

Express P_CCl4 in terms of P_Cl2

0.76 = (P_Cl2)^2 / (P_CCl4)

0.76P_CCl4 = (P_Cl2)^2

Ptotal = P_Cl2 = 1.9 atm

Solve for P_CCl4

P_CCl4 = 4.75 atm<span />
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