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Natalija [7]
3 years ago
9

Complete the following reaction sequence by drawing in the neutral reagents and products where necessary. The product of this re

action has a molecular formula of C7H6O2 and has a 1H NMR spectrum (CDCl3) of ~12.1 (s), 8.1 (m), and 7.6–7.4 (m) ppm. *Show covalent bonds in all compounds.

Chemistry
1 answer:
alexgriva [62]3 years ago
5 0

Answer:

Benzoic acid

Explanation:

In this case we have a Grignard reaction in which we go from a formula of C6H5Br to C7H6O2. In other words, we add 1 carbon to the molecule. The only way to add one carbon to this molecule is using CO_2 as a reagent. When this compound is used as electrophile a carboxylic acid is produced.

Respect to the NMR info, we have a <u>downfield singlet signal</u> at 12.1 ppm which is characteristic of the <u>acid hydrogens</u> in the carboxylic acids (see figure 1). When a carboxylic group is added to the benzene we will obtain the <u>benzoic acid</u> which fits with the formula and the NMR info given.

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Four different groups attached to it. A chiral carbon is an asymmetric carbon.
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Grinding quartz crystals down to produce sand is an example of a
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-physical change
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3 years ago
Calculate the weight percent of ascorbic acid in a tablet of Vitamin C from the following data:A 80 mg sample of a crushed Vitam
Lina20 [59]

Answer:

The Answer is 88%

Explanation:

The balanced ionic equation of the reaction

   IO^{3- }+ 8 I^- + 6 H^+ => 3 I^{3- }+ 3 H_2O

  I^{3-} + 2 S_2O_3^{2-} => 3 I^- + S_4O_6^{2-}

 

  C_6H_8O_6 + I^{3- }+ H_2O => C_6H_6O_6 + 3 I^- + 2 H^+

Looking at the above reactions

   The original number of moles of I^{3-} = 3 × number of moles of IO^{3-}

                                                                = 3 × volume × concentration of KIO_3

Note: The formula for number of moles is volume × concentration

                                                                =3 * \frac{40}{1000} *  0.00653 =0.000784 mol

The number of moles of I^{3-} left after its reaction with ascorbic  acid

                         = \frac{1}{2} x moles of S_2O_3^{2-}

                          = \frac{1}{2} x volume x concentration of    S_2O_3^{2-}

                          = \frac{1}{2}  * \frac{15}{1000} * 0.0510 =0.000383 \ mol

Note: The division by 1000 is to convert mill liter to liter

                             Moles of ascorbic acid = moles of I^{3-} reacted

                           = initial \ moles \ of \  I^{3-} \ - remaining \ moles \ of \ I^{3-}

                           =0.000784 - 0.000383

                          =0.000401 \ mols

              Mass =  moles \ * molar \ mass

Hence

              Mass of ascorbic acid = moles of ascorbic acid × molar mass of ascorbic acid

                                                      = 0.000401* 176.12 = 0.07055\ g

                                                      = 70.55\  mg

 Weight% of ascorbic acid = mass of ascorbic acid/mass of sample x 100%

                                             = 70.55/80  × 100%

                                              = 88.1%

                       

3 0
4 years ago
Imagine that you wanted to make a time capsule in which you would seal important artifacts from your life (pictures, poems, a lo
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Answer:

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Explanation:

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The <u>electronic configuration</u> of argon helps us see why that is the case: With an atomic number of 18, it has an electronic configuration of 1s² 2s² 2p⁶ 3s² 3p⁶. This means the most external orbital is filled with electrons, meaning that there are not unpaired electrons able to react with other substances.

5 0
3 years ago
A single atom of an element has 11 protons, 11 electrons, and 12 neutrons. Which element is it? a V b Na c Mg d Se
wel

Answer:

B.  Na

Explanation:

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8 0
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