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bonufazy [111]
3 years ago
12

Why is liquid water freezing at a temperature below its freezing point a spontaneous process?

Chemistry
1 answer:
Dennis_Churaev [7]3 years ago
7 0
Well , when liquid water is kept at a temperature below it's freezing point it turns into ice. As the temperature of surrounding is below freezing point , it freezes. Hence the liquid water freezing at a temperature below its freezing point is a spontaneous process.
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An apparatus consists of a 4.0 dm^3 flask containing nitrogen gas at 25°c and 803 kPa, it is joined by a valve to a 10.0dm^3 fla
krok68 [10]

Answer:

so total pressure is = 261.92 kPa

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partial pressure of N2 gas = 227  kPa

Explanation:

PV = nRT  

n = PV / RT

as we know that 1dm3 = 1 Liter  

smaller flask before mixing

ideal gas constant

n = (803 kPa) x (4L) / ((8.3144621 L kPa/K mol) x (25 + 273 K))  

n = (3212 kPa L) / ((8.3144621 L kPa/K mol) x (298 K))  

n = (3212 kPa L) /2477.7

n=  1.29 mol

In the larger flask:

n = (47.2 kPa) x (10 L) / ((8.3144621 L kPa/K mol) x (25 + 273 K)) =  

n = (472 kpaL/ 2477.7

n= 0.19 mol  

PV = nRT  

P = nRT / V  

After mixing:

P = (1.29 mol + 0.19 mol) x (8.3144621 L kPa/K mol) x (25+ 273 K) / (4 L + 10 L)  

    = (1.48) x (2477.7 / (14 L)    

    = 261.92 kPa total pressure  

so total pressure is = 261.92 kPa

a)

(261 kPa) x (0.19 mol Ar) / (1.29 + 0.19mol) =    

= 49.59/1.48 = 33.50 Kpa for Arg

b)

(261 kPa total) - (33.50 kPa Ar) = 227  kPa  for N2

partial pressure of Ar gas=  33.50 Kpa

partial pressure of N2 gas = 227  kPa

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