Answer:
A) It must be negative
Explanation:
A spontaneous reaction in Chemistry is that which is proceeding in a particular direction without the intervention of any external effect. As a spontaneous reaction proceeds (which can be relatively slow), free energy ΔG, which is the available energy for work, is released.
Gibbs free energy, ΔG, is released during a spontaneous process and hence the ΔG is negative because the reactants have more free energy than the products, hence, no energy input is needed for the reaction to proceed forward but rather an energy output. This is what makes a negative ΔG depict a spontaneous reaction.
<span>B.)the rate of reaction</span>
Answer: The actual free-energy change for the reaction -8.64 kJ/mol.
Explanation:
The given reaction is as follows.
Fructose 1,6-bisphosphate
Glyceraldehyde 3-phosphate + DHAP
For the given reaction,
is 23.8 kJ/mol.
As we know that,

Here, R = 8.314 J/mol K, T = 
= (37 + 273) K
= 310.15 K
Fructose 1,6-bisphosphate =
M
Glyceraldehyde 3-phosphate =
M
DHAP =
M
Expression for reaction quotient of this reaction is as follows.
Reaction quotient = ![\frac{[DHAP][\text{glyceraldehyde 3-phosphate}]}{[/text{Fructose 1,6-bisphosphate}]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BDHAP%5D%5B%5Ctext%7Bglyceraldehyde%203-phosphate%7D%5D%7D%7B%5B%2Ftext%7BFructose%201%2C6-bisphosphate%7D%5D%7D)
Q = 
= 
Now, we will calculate the value of
as follows.
= 
= -8647.73 J/mol
= -8.64 kJ/mol
Thus, we can conclude that the actual free-energy change for the reaction -8.64 kJ/mol.
Answer:
T = 401.6 K
Explanation:
Given reaction:

The thermodynamic parameters; ΔG°, ΔH° and ΔS° are related via the Gibbs -Helmholtz equation given as:

For a given reaction, the gibbs free energy change ΔG° is related to the equilibrium constant K as:

It is given that K = 1,
Therefore,

Substituting for ΔG° in equation (1)


