Answer:
Option D, Natural Process
Explanation:
The following happens in all the below given processes -
a) Photosynthesis – In photosynthesis, CO2 taken by plant react with water in presence of sunlight to produce glucose and oxygen. No carbonate is formed in this process.
b) Chemical process – Chemical process are not necessarily natural process and since Jesse wants to know process of conversion of CO2 to carbonate in atmosphere, therefore this should be a natural process.
c) Litterfall – it is related to falling of dead leaves from plant and has no relevance with carbonate formation.
d) Natural process – Natural processes helps the formation of carbonate from CO2 present in atmosphere
A series of chemical reactions are involved
Step 1 – Carbon in atmosphere is dissolved by rain/water to form carbonic acid
CO2 + H2O -> H2CO3 (carbonic acid)
Step 2 – Carbonic acid causes weathering of rock thereby producing bi carbonate ions
H2CO3 + H2O + silicate minerals -> HCO3- + Mineral cations + clays
Step 3 Carbonate is precipitated from bicarbonate ions
Mineral + 2HCO3- -> MineralCO3 + CO2 + H2O
Thus, Option D is correct.