It is chloroplast because thats where everything happens and works
When one phosphate group is removed by breaking a phosphoanhydride bond in a process called hydrolysis, energy is released, and ATP is converted to adenosine diphosphate (ADP). Likewise, energy is also released when a phosphate is removed from ADP to form adenosine monophosphate (AMP)
The stem has more things to transport that's why it has more vascular bundles. The roots only get water from the ground and moving nutrients from the soil to transfer it to the stem. Having more vascular bundles helps the stems to transfer things to leaves and other parts of the plants.