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goldfiish [28.3K]
3 years ago
14

If 1.50 μg of co and 6.80 μg of h2 were added to a reaction vessel, and the reaction went to completion, how many gas particles

would there be in the reaction vessel assuming no gas particles dissolve into the methanol?
Chemistry
2 answers:
Vlada [557]3 years ago
6 0
To determine the number of gas particles in the vessel we add all of the components of the gas. For this, we need to convert the mass to moles by the molar mass. Then, from moles to molecules by the avogadro's number.

1.50x10^-6 ( 1 / 28.01) (6.022x10^23) = 3.22x10^16 molecules CO


6.80x10^-6 ( 1 / 2.02) (6.022x10^23) = 2.03x10 18 molecules H2

Totol gas particles = 2.05x10^18 molecules

Vladimir [108]3 years ago
6 0

<u>Answer:</u> The number of gas particles remained in the vessel is 13.81\times 10^{17}

<u>Explanation:</u>

To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}      .....(1)

  • <u>For CO:</u>

Given mass of CO = 1.50\mu g=1.50\times 10^{-6}g       (Conversion factor:  1\mu g=10^{-6}g  )

Molar mass of CO = 28 g/mol

Putting values in equation 1, we get:

\text{Moles of CO}=\frac{1.50\times 10^{-6}g}{28g/mol}=0.053\times 10^{-6}mol

  • <u>For hydrogen gas:</u>

Given mass of hydrogen gas = 6.8\mu g=6.8\times 10^{-6}g

Molar mass of hydrogen gas = 2 g/mol

Putting values in equation 1, we get:

\text{Moles of hydrogen gas}=\frac{6.8\times 10^{-6}g}{2g/mol}=2.4\times 10^{-6}mol

The chemical equation for the reaction of carbon monoxide and hydrogen gas follows:

CO+2H_2\rightarrow CH_3OH

By Stoichiometry of the reaction:

1 mole of carbon monoxide reacts with 2 moles of hydrogen gas.

So, 0.053\times 10^{-6} moles of carbon monoxide will react with = \frac{2}{1}\times 0.053\times 10^{-6}=0.106\times 10^{-6}mol of hydrogen gas.

As, given amount of hydrogen gas is more than the required amount. So, it is considered as an excess reagent.

Thus, carbon monoxide is considered as a limiting reagent because it limits the formation of product. and it is completely consumed in the reaction.

  • Amount of excess reagent (hydrogen gas) left = (2.4-0.106)\times 10^{-6}=2.294\times 10^{-6} moles

According to mole concept:

1 mole of an element or compound contains 6.022\time 10^{23}  number of particles.

So, 2.294\times 10^{-6}moll of hydrogen gas will contain = 2.294\times 10^{-6}\times 6.022\times 10^{23}=13.81\times 10^{17} number of particles.

Hence, the number of gas particles remained in the vessel is 13.81\times 10^{17}

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uranmaximum [27]

Answer: - 25.8 kJ

The overall process of interest in the question is the following

Hg (g) (650 K) → Hg (l) (297 K)

However, for mercury to pass from a gaseous state in 650 K to a liquid state in 297 K, it must go through a series of steps:

Step 1. Gaseous mercury at 650 K should cool down to 629.88 K, temperature corresponding to the vaporization temperature  of this substance.

Step 2. Gaseous mercury goes to liquid state at 629.88 K .

Step 3. The liquid mercury at 629.88 K is cooled until it reaches 297 K.

This series of steps can be represented through the following <u>diagram</u>:

Hg (g) (650 K) → Hg (g) (629.88 K) → Hg (l) (629.88 K) → Hg (l) (297 K)

                        (1)                             (2)                           (3)

Then the total heat involved in the process will be equal to the sum of the heats inherent to steps 1, 2 and 3. We proceed to calculate the heats for each of the steps.

Step 1:

The heat in step 1 will be given by

Q = n Cp ΔT

where n is the number of moles of mercury, Cp is the heat capacity and ΔT is equal to the difference between the temperatures at the end (T₂) and at the beginning of the process (T₁), that is to say

ΔT = T₂ - T₁

You should know that the <u>heat capacity or thermal capacity is the energy needed to increase the temperature of a certain substance in a unit of temperature.</u> The heat capacity of mercury is Cp = 27.983 J / mol K

Then the heat in step 1 will be,

Q₁ =  75.0 g x \frac{1 mol}{200.59 g} x 27.983 \frac{J}{mol K} x (629.88 K - 650 K)

→ Q₁ = - 210.5 J

Step 2:

In this step a change in the state of the mercury occurs, since it condenses from a gaseous state to a liquid state. In this case the heat involved in the process will be given by ,

Q = - n ΔHvap

where ΔHvap is the enthalpy of vaporization. <u>The enthalpy of vaporization is the amount of energy necessary for the mass unit of a substance that is in equilibrium with its own vapor at a pressure of one atmosphere to pass completely from the liquid state to the gaseous state.</u> Therefore, to determine the energy necessary for the mercury to pass from gaseous state to liquid,<u> the negative of the enthalpy of vaporization must be taken</u>, as it is done in the previous equation with the minus sign that is placed.

The enthalpy of vaporization of mercury is ΔHvap = 59.11 kJ/mol

Then the heat in step 2 will be,

Q₂ =  - 75.0 g x \frac{1 mol}{200.59 g} x 59.11 \frac{kJ}{mol}

→ Q₂ = 22.10 kJ → Q₂ = 22100 J

Step 3:

The heat in step 3 will be

Q₃ = n Cp ΔT  = 75.0 g x \frac{1 mol}{200.59 g} x 27.983 \frac{J}{mol K} x (297 K - 629.88 K)

→ Q₃ = - 3483 J

Finally the heat involved in the overall process will be ,

Q = Q₁ + Q₂ + Q₃ = - 210.5 J - 22100 J - 3483 J = - 25794 J

→ Q = - 25.8 kJ

So,<u> the heat lost when 75.0 g of mercury vapor at 650 K condenses to a liquid at 297 K is - 25.8 K</u>

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