#7 is D because you move the decimal 4 places
Answer:
1) ΔG°r(298 K) = - 28.619 KJ/mol
2) ΔG°r will decrease with decreasing temperature
Explanation:
- CO(g) + H2O(g) → H2(g) + CO2(g)
1) ΔG°r = ∑νiΔG°f,i
⇒ ΔG°r(298 K) = ΔG°CO2(g) + ΔG°H2(g) - ΔG°H2O(g) - ΔG°CO(g)
from literature, T = 298 K:
∴ ΔG°CO2(g) = - 394.359 KJ/mol
∴ ΔG°CO(g) = - 137.152 KJ/mol
∴ ΔG°H2(g) = 0 KJ/mol........pure substance
∴ ΔG°H2O(g) = - 228.588 KJ/mol
⇒ ΔG°r(298 K) = - 394.359 KJ/mol + 0 KJ/mol - ( - 228.588 KJ/mol ) - ( - 137.152 KJ7mol )
⇒ ΔG°r(298 K) = - 28.619 KJ/mol
2) K = e∧(-ΔG°/RT)
∴ R = 8.314 E-3 KJ/K.mol
∴ T = 298 K
⇒ K = e∧(-28.619/(8.314 E-3)(298) = 9.624 E-6
⇒ ΔG°r = - RTLnK
If T (↓) ⇒ ΔG°r (↓)
assuming T = 200 K
⇒ ΔG°r(200 K) = - (8.314 E-3)(200)Ln(9.624E-3)
⇒ ΔG°r (200K) = - 19.207 KJ/mol < ΔG°r(298 K) = - 28.619 KJ/mol
C is a mixture!!!!!!!!!!!!!
The concept used here is the Le Chatelier's principle. When a disturbance is introduced to the system, it favors the direction of reaction that minimizes the disturbance to regain equilibrium.
In endothermic reactions, the forward reaction is favored when the temperature is low. Otherwise, the reverse reaction is favored. When you add the amounts of substances on the reactant side, more products would formed favoring the forward reaction. If you increase concentration on the product side, you form more reactants so it would favor the reverse reaction. Lastly, since 10 moles of gases are needed in the reactant side, it would be favored during high pressure reaction.
