What ion will be formed by the selenium atom shown below when it has a stable set of valence electrons?
1 answer:
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Answer : The rate law for the overall reaction is,
Explanation :
Rate law : It is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.
As we are given the mechanism for the reaction :
Step 1 : (slow)
Step 2 : (fast)
Overall reaction :
The rate law expression for overall reaction should be in terms of .
As we know that the slow step is the rate determining step. So,
The slow step reaction is,
The expression of rate law for this reaction will be,
Hence, the rate law for the overall reaction is,
Answer:
0.33 mol/kg NH₃
Explanation:
Data:
b(NH₃) = 0.33 mol/kg
b(Na₂SO₄) = 0.10 mol/ kg
Calculations:
The formula for the boiling point elevation ΔTb is
i is the van’t Hoff factor — the number of moles of particles you get from a solute.
(a) For NH₃,
The ammonia is a weak electrolyte, so it exists almost entirely as molecules in solution.
1 mol NH₃ ⟶ 1 mol particles
i ≈ 1, and ib = 1 × 0.33 = 0.33 mol particles per kilogram of water
(b) For Na₂SO₄,
Na₂SO₄(aq) ⟶ 2Na⁺(aq) + 2SO₄²⁻(aq)
1 mol Na₂SO₄ ⟶ 3 mol particles
i = 1 and ib = 3 × 0.10 = 0.30 mol particles per kilogram of water
The NH₃ has more moles of particles, so it has the higher boiling point.