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Cloud [144]
3 years ago
6

What is the maximum mass in grams of NH3 that can be produced by the reaction of of 2.5 g N2 with 2.5 g of H2 via the equation b

elow?
N2 (g) + 3 H2 (g) → 2 NH3 (g)
Chemistry
1 answer:
andrezito [222]3 years ago
6 0

Answer: The mass of NH_3 produced is, 3.03 grams.

Explanation : Given,

Mass of N_2 = 2.5 g

Mass of H_2 = 2.5 g

Molar mass of N_2 = 28 g/mol

Molar mass of H_2 = 2 g/mol

First we have to calculate the moles of N_2 and H_2.

\text{Moles of }N_2=\frac{\text{Given mass }N_2}{\text{Molar mass }N_2}=\frac{2.5g}{28g/mol}=0.089mol

and,

\text{Moles of }H_2=\frac{\text{Given mass }H_2}{\text{Molar mass }H_2}=\frac{2.5g}{2g/mol}=1.25mol

Now we have to calculate the limiting and excess reagent.

The balanced chemical equation is:

N_2(g)+3H_2(g)\rightarrow 2NH_3(g)

From the balanced reaction we conclude that

As, 1 mole of N_2 react with 3 mole of H_2

So, 0.089 moles of N_2 react with 0.089\times 3=0.267 moles of H_2

From this we conclude that, H_2 is an excess reagent because the given moles are greater than the required moles and N_2 is a limiting reagent and it limits the formation of product.

Now we have to calculate the moles of NH_3

From the reaction, we conclude that

As, 1 mole of N_2 react to give 2 mole of NH_3

So, 0.089 mole of N_2 react to give 0.089\times 2=0.178 mole of NH_3

Now we have to calculate the mass of NH_3

\text{ Mass of }NH_3=\text{ Moles of }NH_3\times \text{ Molar mass of }NH_3

Molar mass of NH_3 = 17 g/mole

\text{ Mass of }NH_3=(0.178moles)\times (17g/mole)=3.03g

Therefore, the mass of NH_3 produced is, 3.03 grams.

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The iodide ion reacts with hypochlorite ion (the active ingredient in chlorine bleaches) in the following way: OCl−+I−→OI−+Cl− T
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Answer :

(a) The rate law for the reaction is:

\text{Rate}=k[OCl^-]^1[I^-]^1

(b) The value of rate constant is, 60.4M^{-1}s^{-1}

(c) rate of the reaction is 6.52\times 10^{-5}Ms^{-1}

Explanation :

Rate law : It is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.

For the given chemical equation:

OCl^-+I^-\rightarrow OI^-+Cl^-

Rate law expression for the reaction:

\text{Rate}=k[OCl^-]^a[I^-]^b

where,

a = order with respect to OCl^-

b = order with respect to I^-

Expression for rate law for first observation:

1.36\times 10^{-4}=k(1.5\times 10^{-3})^a(1.5\times 10^{-3})^b ....(1)

Expression for rate law for second observation:

2.72\times 10^{-4}=k(3.0\times 10^{-3})^a(1.5\times 10^{-3})^b ....(2)

Expression for rate law for third observation:

2.72\times 10^{-4}=k(1.5\times 10^{-3})^a(3.0\times 10^{-3})^b ....(3)

Dividing 1 from 2, we get:

\frac{2.72\times 10^{-4}}{1.36\times 10^{-4}}=\frac{k(3.0\times 10^{-3})^a(1.5\times 10^{-3})^b}{k(1.5\times 10^{-3})^a(1.5\times 10^{-3})^b}\\\\2=2^a\\a=1

Dividing 1 from 3, we get:

\frac{2.72\times 10^{-4}}{1.36\times 10^{-4}}=\frac{k(1.5\times 10^{-3})^a(1.5\times 10^{-3})^b}{k(1.5\times 10^{-3})^a(3.0\times 10^{-3})^b}\\\\2=2^b\\b=1

Thus, the rate law becomes:

\text{Rate}=k[OCl^-]^a[I^-]^b

a  = 1 and b = 1

\text{Rate}=k[OCl^-]^1[I^-]^1

Now, calculating the value of 'k' (rate constant) by using any expression.

1.36\times 10^{-4}=k(1.5\times 10^{-3})(1.5\times 10^{-3})

k=60.4M^{-1}s^{-1}

Now we have to calculate the rate for a reaction when concentration of OCl^-  and I^-  is 1.8\times 10^{-3}M and 6.0\times 10^{-4}M respectively.

\text{Rate}=k[OCl^-][I^-]

\text{Rate}=(60.4M^{-1}s^{-1})\times (1.8\times 10^{-3}M)(6.0\times 10^{-4}M)

\text{Rate}=6.52\times 10^{-5}Ms^{-1}

Therefore, the rate of the reaction is 6.52\times 10^{-5}Ms^{-1}

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