Answer: Option (d) is the correct answer.
Explanation:
Steps involved for the given reaction will be as follows.
Step 1: 
(fast)
Rate expression for step 1 is as follows.
Rate = k ![[NO]^{2}](https://tex.z-dn.net/?f=%5BNO%5D%5E%7B2%7D)
Step 2: 
This step 2 is a slow step. Hence, it is a rate determining step.
Step 3. 
(fast)
Here, 
is intermediate in nature.
All the steps are bimolecular and it is a second order reaction. Also, there is no catalyst present in this reaction.
Thus, we can conclude that the statement step 1 is the rate determining step, concerning this mechanism is not directly supported by the information provided.
increases my factor of 10
Given that 1 mole contains 6.02x10^23 molecules, 3.0x10^23 is just around half a mole. Then we check the number of moles for each choice:
A. This is approximately half a mole, since the molar mass of Br2 is 159.8 g/mol.
B. He has a molar mass around 4 g/mol, so this is 1 mole.
C. H2 has a molar mass of 2.02 g/mol, so this is 2 moles.
D. Li has a molar mass of around 6.97 g/mol, so this is around 2 moles.
Therefore the only choice that fits is A. 80 g of Br2.
The new pressure is 81.675 torr
Since temperature and moles are held constant, we use Boyle's Law:
A gas law known as Boyle's law asserts that a gas's pressure is inversely proportional to its volume when it is held at a fixed temperature and of a given mass.
To put it another way, as long as the temperature and volume of the gas remain constant, the pressure and volume of the gas are inversely proportional to one another.
The Anglo-Irish chemist Robert Boyle proposed Boyle's law in the year 1662.
P1V1=P2V2. Simply plug in your values. The units can remain in torr. Converting to atmospheres is not needed.
(242 torr)(27.0 L)=P2(80.0 L)
P2=[(242)(27)]/80 = 81.675 torr
Hence The new pressure is 81.675 torr
Learn more about Boyle's Law here
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