The word "the" starts the name of the movie/ book/ piece, therefore, the letter "T" of the word "the" MUST be written in capital letters sice the begining of any sentence/name must be capital.
The answer would be A.) the, as it needs to be capitalized at the beginning of the title. Red Chief is correct as, with context, appears to be a noun, a name. C is correct as it is the beginning of a sentence. D is correct as it is in the title and does not follow the rules of "of","and", etc.