Explanation:
Natural materials are those that are found in nature and have not been made by humans. By comparison, synthetic materials are man-made and cannot be found in nature. Synthetic products are usually created in laboratories by mixing different chemicals, or prepared compounds and substances made in a laboratory.
Answer is Buffer zone
Reason - example is undeveloped land separating the shopping center from a residential neighborhood.
Humidity is the amount of Water vapour In the air.
A superpower is a country which is very strong internationally and which exercises its power and influence on the neighboring countries.
Among the options, Greenland has too small population to be a superpower, and Mexico is a developing economy still. Both US and Canada are strong economically, but it's the superpower.