Supplementary Angles:

Arithmetically speaking, the closest 2 supplementary angles can get (in 3 and 2 digits respectively) is the upwritten.
Complementary Angles:

Simply, in this case, for angles to be numerically as close as possible - make both the angles 45°.
The answer is 80.5 ... 805 / 5
Remember that, for independent events, the probability that both occurr is the product of the individual probabilities.
a) Probability of being contacted: 78% = 0.78
Probaility of refusing: 1 - 22% = 1 -0.22 = 0.78
Combined probability: 0.78*0.78 = 0.6084
b) The probability of failing to contact or making contact and not geeting them to agree 1 - the probability of contacting and getting them to agree.
The probabilityof contacting and getting them to agree is 0.78*0.22 = 0.1716
The the answer to this question is 1 - 0.1716 = 0.8284