What is the oxidation number of Nitrogen in HNO2? +1 -1 +3 -3
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Given that, an experiment to measure the enthalpy change for the reaction of aqueous copper(II) sulfate, CuSO4(aq) and zinc, Zn(s) was carried out in a coffee cup calorimeter; the heat of the reaction in the whole system is calculated to be 2218.34 kJ
Heat of reaction (i.e enthalpy of reaction) is the quantity of heat that is required to be added or removed when a chemical reaction is taken place in order to maintain all of the compounds present at the same temperature.
The formula used to calculate the heat of the reaction can be expressed as follows:
Q = mcΔT
where:
- Q = quantity of heat transfer
- m = mass
- c = specific heat of water = 4.18 kJ/g °C (constant)
- ΔT = change in temparature
From the information given:
- The initial temperature (T₁) = 25° C
- The final temperature (T₂) = 91.5° C
∴
The change in temperature i.e. ΔT = T₂ - T₁
ΔT = 91.5° C - 25° C
ΔT = 66.5° C
The number of moles of CuSO₄ = 1.00 mol/dm³ × 50.0 cm³
= 0.05 moles
- Since the molar mass of CuSO₄ = 159.609 g/mol
Then;
Using the relation:
By crossing multiplying;
mass of CuSO₄ = number of moles of CuSO₄ × molar mass of CuSO₄
mass of CuSO₄ = 0.05 moles × 159.609 g/moles
mass of CuSO₄ = 7.9805 grams
∴
Using the formula from above:
Q = mcΔT
Q = 7.9805 g × 4.18 kJ/g °C × 66.5° C
Q = 2218.34 kJ
Therefore, we can conclude that the heat of the reaction is 2218.34 kJ
Learn more about the chemical reaction here:
The maximum height at which nitrogen molecule will go before coming to rest is 14 kilometers.
Given:
The nitrogen gas molecule with a temperature of 330 Kelvins is released from Earth's surface to travel upward.
To find:
The maximum height of a nitrogen molecule when released from the Earth's surface before coming to rest.
Solution:
- The maximum height attained by nitrogen gas molecule = h
- The temperature of nitrogen gas particle = T = 330 K
The average kinetic energy of the gas particles is given by:
The nitrogen molecule at its maximum height will have zero kinetic energy as all the kinetic energy will get converted into potential energy
- The potential energy at height h =
- Molar mass of nitrogen gas = 28.0134 g/mol
- Mass of nitrogen gas molecule = m
- The acceleration due to gravity = g = 9.8 m/s^2
- The maximum height attained by nitrogen gas molecule = h
- The potential energy is given by:
The maximum height at which nitrogen molecule will go before coming to rest is 14 kilometers.
Learn more about the average kinetic energy of gas particles here: