The transition word which is not correctly used in the passage is moreover.
As you can see in this sentence (<span>Moreover the invention of television and digital media, such as the Internet, most ads appeared in newspapers, magazines, and the radio.), something is wrong - the sentence doesn't sound natural or grammatical. This is why that word is the one which is used incorrectly, whereas the other sentences are good.</span>
The answer is number 4) These numbers show that teenagers care about others.
Sentences 1-3 show evidence to support the main argument, which is that teenagers help others. Sentence 1 gives an individual example, and on sentences 2 and 3, it presents statistical data.
It could possible be ironic because the rest of the world was technically already "discovered", but just not by the Europeans specifically. Therefore it is ironic, simply because they are Naive
Tom told him that Gatsby was the one who was driving the vehicle.