i can help you with 1 .Sorry that i cant do 2 because number 2 doesnt have all the question in the photo.
<span>An ionic crystal consists of ions bound together by electrostatic attraction. The arrangement of ions in a regular, geometric structure is called a crystal lattice. Examples of such crystals are the alkali halides, which include: potassium fluoride (KF)</span>
First, have common denominators.
1/4 = 3/12
2/3 = 8/12
8/12 - 3/12 = 5/12 or 1,010 gallon
1,010/5 gallon = 1/12 full
202 gallons = 1/12 full
7/12 needed until full ⇒ 7*202 = 1,414 gallons