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Gnom [1K]
3 years ago
12

Consider the following reaction: AB(s)⇌A(g)+B(g) . At equilibrium, a 10.9 L container at 650 K contains A(g) at a pressure of 0.

126 atm and B(g) at a pressure of 0.23 atm. The container is then compressed to half of its original volume. What is the pressure of B(g) after the reaction reattains equilibrium? Express your answer numerically in atm.
Chemistry
1 answer:
irina1246 [14]3 years ago
4 0

Answer:

pA = 0.095 atm

pB = 0.303 atm

Explanation:

Step 1: the reaction

AB(s) ⇔ A(g) + B(g)

Kp = pA * pB

⇒ with Kp = equilibrium constant

Kp = 0.126 * 0.23  ⇒ Kp = 0.02898

Since the container will be compressed to half of its original volume, means that he pressure will be doubled.

⇒pA = 0.252

⇒pB =0.46

To establish this equilibrium, each pressure has to be lowered by x

⇒pA = 0.252 - x

⇒pB = 0.46 - x

Kp = 0.02898 = (0.252 - x)(0.46-x)

0.02898 = 0.11592 - 0.252x -0.46x + x²

-x² + 0.712x - 0.08694 = 0

D= b² - 4ac

⇒ D = 0.712² -4*(-1) *(-0.08694) = 0.506944‬ -0.34776‬ =0.159184

x = (-b ± √D)/2a  

x = (-0.712 ± √0.159184)/(2*-1)  = (-0.712 ± 0.398978696)/-2

x = 0.156510652 or x= 0.555489348

x = 0.555489348 is impossble or the pressure would be negative

x=0.156510652

pA =0.252 - 0.156510652 = 0.095489348 atm

pB = 0.46 - 0.156510652 = 0.303489348 atm

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4 0
3 years ago
An acid with molar mass 84.48 g/mol is titrated with 0.650 M KOH. What volume of KOH solution is needed to titrate 1.70 grams of
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Answer:

V=0.0310L=3.10mL

Explanation:

Hello.

In this case, since the acid is monoprotic and the KOH has one hydroxyl ion only, we can see that at the equivalence point the moles of both of them are the same:

n_{acid}=n_{KOH}

Thus, since we are given 1.70 g of the acid, we compute the moles of acid that were titrated:

n_{acid}=1.70g*\frac{1mol}{84.48g}=0.0201mol

Which equal the moles of KOH. In such a way, since the molarity is defined as moles over liters (M=n/V), the liters are moles over molarity (V=n/M), thus, the resulting volume is:

V=\frac{0.0201mol}{0.650mol/L}\\\\V=0.0310L=3.10mL

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Answer:

See Explanation

Explanation:

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