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denis-greek [22]
3 years ago
9

3. Decomposition of a sample of KCIO3(s) produced 25.2 mL of 020, at a temperature of

Chemistry
1 answer:
dsp733 years ago
6 0

The volume of Oxygen gas=26.712 ml

<h3>Further explanation</h3>

The pressure constant = 89.6 kPa, so we use Charles's Law  

<em>When the gas pressure is kept constant, the gas volume is proportional to the temperature  </em>

\tt \dfrac{V_1}{T_1}=\dfrac{V_2}{T_2}

V₁=25.2 ml

T₁=27+273=300 K

T₂=45+273=318 K

\tt V_2=\dfrac{V_1\times T_2}{T_1}\\\\V_2=\dfrac{25.2\times 318}{300}\\\\V_2=26.712~ml

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The given question is incomplete. The complete question is:

When 282. g of glycine (C2H5NO2) are dissolved in 950. g of a certain mystery liquid X, the freezing point of the solution is 8.2C lower than the freezing point of pure X. On the other hand, when 282. g of ammonium chloride are dissolved in the same mass of X, the freezing point of the solution is 20.0C lower than the freezing point of pure X. Calculate the van't Hoff factor for ammonium chloride in X.

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Explanation:

Depression in freezing point is given by:

\Delta T_f=i\times K_f\times m

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m= molality

8.2^0C=1\times K_f\times \frac{\text{mass of solute}}{\text{molar mass of solute}\times \text{weight of solvent in kg}}

Weight of solvent (X)= 950 g = 0.95 kg

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ii) 20.0^0C=i\times \times \frac{\text{mass of solute}}{\text{molar mass of solute}\times \text{weight of solvent in kg}}

Weight of solvent (X)= 950 g = 0.95 kg

Molar mass of solute (ammonium chloride) = 53.49 g/mol

Mass of solute (ammonium chloride) = 282 g

20.0^0C=i\times 2.07\times \frac{282g}{53.49g/mol\times 0.95kg}

i=1.74

Thus the van't Hoff factor for ammonium chloride is 1.74

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