Question options:
a) 2.05
b) 0.963
c) 0.955
d) 1.00
Answer:
b) 0.963
Explanation:
H2SO4→ HSO4- + H3O+
HSO4- + H2O ⇌ SO42- + H3O+
Construct ICE table:
HSO4- (aq) + H2O ⇌ SO42- (aq) + H3O+ (aq)
I 0.1 solid & 0 0.1
C -x liquid + x + x
E 0.1 - x are ignored x 0.1 + x
Calculate x
Ka = products/reactants
= ![\frac{[SO42-] [H3O+]}{[HSO4-]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BSO42-%5D%20%5BH3O%2B%5D%7D%7B%5BHSO4-%5D%7D)
0.011 = 
0.011 x (0.1 -x) = o.1x + x^2
0.0011 - 0.011 x - o.1x - x^2 = 0
0.0011 - 0.011 x - x^2 = 0
Use formula to solve for quadratic equation
x = 
/ 2a
a = -1, b = -0.111, c = 0.001
Solve for x
x = ![\sqrt[-(-o.111)]{(-0.111)^2 - 4(-1) (0.0011) }](https://tex.z-dn.net/?f=%5Csqrt%5B-%28-o.111%29%5D%7B%28-0.111%29%5E2%20-%204%28-1%29%20%280.0011%29%20%7D)
/ 2(-1)
x = 0.111 +,- 
/ -2
x = 0.111 +,- 
/ -2
x = 
x = 
, x = 
x = 
, x = 
x = - 0.12015 , x = 0.00915
x cannot be negative, so
x = 0.00915 M
Calculate [H3O+]
[H3O+] = 0.1 M + x
[H3O+] = 0.1 M + 0.00915 M
[H3O+] = 0.10915 M
Clculate pH
pH = - log [ H3O+]
pH = - log [ 0.10915]
pH = 0.963
Answer:
Reaction mechanism has been given below
Explanation:
- Propanoyl chloride contains an electrophilic carbonyl center to give nucleophilic acyl substitution reaction by removing Cl group with a strong nucleophile like methylmagnesium bromide.
- Two equivalent of methyl magnesium bromide react with cabonyl center followed by protonation of negatively charged oxygen atom gives 2-methyl-2-butanol.
- In the first step, nucleophilic acyl substituion occurs. In the second step, nucleophilic addition occurs. In the third step, protonation occurs.
- Reaction mechanism has been shown below.
Answer:
a) 
b) 
c) 
Explanation:
Hello,
In this case, in each reaction we must subtract the Gibbs free energy of formation the reactants to the Gibbs free energy of formation of the products considering each species stoichiometric coefficients. In such a way, the Gibbs free energy of formations are:
So we proceed as follows:
a)
b)
c)
Regards.
It will approximately take 2 hours and 50 minutes
Nonrenewable is when if your recyle something it can't be made into something new and renewable is when something recycled it can be made into something new
