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3 years ago

What are defect of mendeleevs perodic table

Chemistry

1 answer:

astraxan [27]3 years ago

5 0

Answer:

i.elements not obeying increasing atomic mass. ii.properties and uneven grouping.

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The gas-phase reaction follows an elementary rate law and is to be carried out first in a PFR and then in a separate experiment

astraxan [27]

Answer:

The activation energy is $=8.1\,kcal\,mol^{-1}$

Explanation:

The gas phase reaction is as follows.

$A \rightarrow B+C$

The rate law of the reaction is as follows.

$-r_{A}=kC_{A}$

The reaction is carried out first in the plug flow reactor with feed as pure reactant.

From the given,

Volume "V" = $10dm^{3}$

Temperature "T" = 300 K

Volumetric flow rate of the reaction $v_{o}=5dm^{3}s$

Conversion of the reaction "X" = 0.8

The rate constant of the reaction can be calculate by the following formua.

$V= \frac{v_{0}}{k}[(1+\epsilon )ln(\frac{1}{1-X}-\epsilon X)]$

Rearrange the formula is as follows.

$k= \frac{v_{0}}{V}[(1+\epsilon )ln(\frac{1}{1-X}-\epsilon X)]............(1)$

The feed has Pure A, mole fraction of A in feed $y_{A_{o}}$ is 1.

$\epsilon =y_{A_{o}}\delta$

$\delta$ = change in total number of moles per mole of A reacte.

$=1(2-1)=1$

Substitute the all given values in equation (1)

$k=\frac{5m^{3}/s}{10dm^{3}}[(1+1)ln \frac{1}{1-0.8}-1 \times 0.8] = 1.2s^{-1}$

Therefore, the rate constant in case of the plug flow reacor at 300K is $1.2s^{-1}$

The rate constant in case of the CSTR can be calculated by using the formula.

$\frac{V}{v_{0}}= \frac{X(1+\epsilon X)}{k(1-X)}.............(2)$

The feed has 50% A and 50% inerts.

Hence, the mole fraction of A in feed $y_{A_{o}}$ is 0.5

$\epsilon =y_{A_{o}}\delta$

$\delta$ = change in total number of moles per mole of A reacted.

$=0.5(2-1)=0.5$

Substitute the all values in formula (2)

$\frac{10dm^{3}}{5dm^{3}}=\frac{0.8(1+0.5(0.8))}{k(1-0.8)}=2.8s^{-1}$

Therefore, the rate constant in case of CSTR comes out to be $2.8s^{-1}$

The activation energy of the reaction can be calculated by using formula

$k(T_{2})=k(T_{1})exp[\frac{E}{R}(\frac{1}{T_{1}}-\frac{1}{T_{2}})]$

In the above reaction rate constant at the two different temperatures.

Rearrange the above formula is as follows.

$E= R \times(\frac{T_{1}T_{2}}{T_{1}-T_{2}})ln\frac{k(T_{2})}{k(T_{1})}$

Substitute the all values.

$=1.987cal/molK(\frac{300K \times320K}{320K \times300K})ln \frac{2.8}{1.2}=8.081 \times10^{3}cal\,mol^{-1}$

$=8.1\,kcal\,mol^{-1}$

Therefore, the activation energy is $=8.1\,kcal\,mol^{-1}$

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3 years ago

The electronegativity is 2.1 for h and 1.9 for pb. based on these electronegativities pbh4 would be expected to

Sedbober [7]

PbH4 will be formed as a result of a polar covalent bond between the H and the Pb.

Since H is more electronegative than the Pb, it is, thus, expected that the H would be able to pull the electron charge towards itself. This will result in the H being negative.

Based on this:
PbH4 would be expected to <span>have polar covalent bonds with a partial negative charges on the H atoms. </span>

8 0

3 years ago

What are defect of mendeleevs perodic table​

What are defect of mendeleevs perodic table