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Vera_Pavlovna [14]
3 years ago
7

What is the pH of a solution with a concentration of 4.2 x 10−5 M H3O+? (4 points)

Chemistry
1 answer:
zheka24 [161]3 years ago
4 0

Answer:

1) b. 4.38

2)  d. 10.7

Explanation:

1) The problem tells us that [H₃O⁺] = 4.2x10⁻⁵ M, and keeping in mind that [H₃O⁺]= [H⁺], we <u>can calculate the pH of the solution</u>:

  • pH = -log[H⁺] = 4.38

2) First we <u>calculate the pOH of the solution</u>:

  • pOH = -log[OH⁻] = -log(4.6x10⁻⁴) = 3.33

Then we <u>calculate the pH</u> using the <em>following formula</em>:

  • pH = 14 - pOH = 14 - 3.33
  • pH = 10.7
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For the following reaction at 600. K, the equilibrium constant, Kp, is 11.5. PCl5(g) equilibrium reaction arrow PCl3(g) + Cl2(g)
Lubov Fominskaja [6]

Answer:

a) pPCl5 = 0.856 atm

b)pPCl5 = 0.0557 atm

pCl2 = pCl3 = 0.800 atm

c)  Ptotal = 1.66 atm

d) 93.5

Explanation:

Step 1: Data given

Temperature = 600 K

Kp = 11.5

Mass of PCl5 = 2.010 grams

Volume of the bulb = 555 mL = 0.555 L

The bulb is heated to 600 K

Step 2: The balanced equation

PCl5(g) ⇄ PCl3(g) + Cl2(g)

Step 3:

a) pv = nrt

⇒with p = the pressure = TO BE DETERMINED

⇒with V = the volume = 0.555 L

⇒ with n =the number of moles PCl5 = 2.010 grams / 208.24 g/mol = 0.00965 moles

⇒ with R = the gas constant = 0.08206 L*atm/mol*K

⇒ with T = the temperature = 600K

p = (0.00965 *0.08206*600)/0.555

pPCl5 = 0.856 atm

b)

The initial pressures

pPCl5 = 0.856 atm

pCl2 = pCl3 = 0 atm

For 1 mol PCl5 we'll have PCl3 and 1 mol Cl2

The pressure at the equilibrium

pPCl5 = (0.856 -x) atm

pCl2 = pCl3 = x atm

Kp = pPCl3 * pCl2/pPCl5  

11.5 = x*x / (0.856 - x)

11.5 = x²/(0.856- x)

x = 0.8003

pPCl5 = (0.856 -x) atm = 0.0557 atm

pCl2 = pCl3 = x atm = 0.800 atm

c) Since x = 0.8003 and PCl3 and PCl2 are x  

Ptotal = 0.8003 + 0.8003 +0.0557 = 1.66 atm

d)

The degree of dissociation = (x / initial pressure PCl5)

(0.8003/0.856) * 100 = 93.5

7 0
4 years ago
Calculate the ph after 0.020 mol hcl is added to 1.00 l of each of the four solutions below.
melisa1 [442]
A) according to this reaction:
by using ICE table:
              NH2OH(aq) + H2O(l) → HONH3+(aq)   + OH-
initial       0.4 M                                       0                    0
change     -X                                          +X                  +X
Equ        (0.4-X)                                         X                    X

when Kb = [OH-][HONH3+]/[NH2OH]  
when we have Kb = 1.1x10^-8 so,
by substitution:
1.1x10^-8 = X^2/(0.4-X) by solving this equation for X 

∴X = 6.6x10^-5 M
∴[OH] = 6.6x10^-5 M 
when POH = - ㏒[OH]
    ∴POH = -㏒(6.6x10^-5)= 4.18
∴PH = 14 - POH = 14 - 4.18
        = 9.82
when PH = -㏒[H+]
∴[H+] = 10^9.82 = 1.5x10^-10 M+0.02molHcl
          = 0.02
∴ the new value of PH = -㏒(0.02)
∴PH = 1.7

B) according to this reaction:
 by using ICE table:
             HONH3+(aq) → H+(aq) + HONH2(aq)
intial     0.4                          0            0
change -X                          +X           +X
Equ       (0.4-X)                    X              X

when Ka HONH3Cl = 9.09x10^-7 
and Ka = [H+][HONH2] / [HONH3+]

So by substitution and we can assume [HONH3+] = 0.4 as the value of Ka is so small so,
9.09x10^-7 = X^2 / 0.4 by solving for X
∴  X = 6 x 10 ^-4
∴[H+] = 6x10^-4
PH = -㏒[H+] 
      = -㏒ (6x10^-4) = 3.22
when [H+] = 6x10^-4 + 0.02 m HCl 
∴new value of PH = -㏒(6x10^-4+0.02)
                               = 1.69
C) when we have pure H2O and PH of water = 7
So we can get [H+] when PH = -㏒[H+]
∴[H+] = 10^-7 + 0.02MHCl
          = 0.02
∴new value of PH = -㏒0.02
                         PH = 1.7
d) when HONH2 & HONH3Cl have the same concentration and Hcl added to them so we can assume that PH=Pka
and when we have Ka for HONH3Cl = 9.09x10^-7 
So we can get the Pka:

Pka = -㏒Ka
       = -㏒9.09x10^-7
       = 6.04
∴PH = 6.04
and because of the concentration of the buffer components, HONH2 & HONH3Cl have 0.4 M and the adding of HCl = 0.02 M So PH will remain very near to 6 






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alexdok [17]
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How many unpaired electrons are there in helium?
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4 years ago
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