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The Nernst equation enables us to identify the cell potential(voltage) in presence of non-standard conditions in a galvanic cell. It can be expressed by using the formula:

$\mathbf{E_{cell} = E_o - \dfrac{0.059}{n} \times log \dfrac{[Fe^+]}{[Mn^{2+}]}}$

where;

n = Number of electrons = 2
$\mathbf{E_o}$ = Initial voltage = 0.77 V
$\mathbf{E_{cell}}$ = Cell voltage = 0.78 V
$\mathbf{[Mn^{2+}]}$ = Manganese concentration = 0.050 M

Replacing the values into the above equation, we have:

$\mathbf{0.78 = 0.77 - \dfrac{0.059}{2} \times log \dfrac{[Fe^{2+}]}{[0.050]}}$

$\mathbf{0.78 -0.77= -0.0296\times log \dfrac{[Fe^{2+}]}{[0.050]}}$

$\mathbf{log^{-1} (-0.3378) = \dfrac{[Fe^{2+}]}{[0.050]}}$

$\mathbf{Fe^{2+} = (0.4594\times 0.050 )\ M}$

$\mathbf{Fe^{2+} =0.02297 \ M }$

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