Answer:
(C) substance B is not involved in the rate-determining step of the mechanism but is involved in subsequent steps.
Explanation:
A. Is incorrect because if the order of the reaction with respect B was one then the rate would increase by the same multiple that B is increased by.
B. If B is reactant then it must be involved in the mechanism of the reaction and in the formation of the product
D. If B was a catalyst then increasing it's amount would affect the rate
E. That is just factually untrue. Effect of reactants on rates can only be found experimentally, not stoichiometrically.
Answer: There will be 41382 J energy must be absorbed by 45.0g of water to increase its temperature from
to
.
Explanation:
Given: Mass = 45.0 g
Initial temperature = 
Final temperature = 
Formula used to calculate heat energy is as follows.

where,
q = heat energy
m = mass of substance
C = specific heat =
(here, for water)
= initial temperature
= final temperature
Substitute the values into above formula as follows.

Thus, we can conclude that there will be 41382 J energy must be absorbed by 45.0g of water to increase its temperature from
to
.
The equation is as follows:
Cyclohexane (C6H12) ⇔ Methyl cyclopentane (C6H12)
The equilibrium constant Kc = 0.143 >>> (1)
Qc is the reaction quotient
where; If Q = K >>>> No shift left or right >>> (2)
Q > K >>>> Reaction shifts left >>> (3)
Q < K >>>> Reaction shifts right >>> (4)
And in our equation; Q = 0.3 / 0.4 = 0.75 >>> (5)
From (1), (3) and (5), Q > Kc
∴ the reaction shifts left
Answer:
New volume is 14.35 mL
Explanation:
When a system of a gas keeps on constant its temperature and number of moles, the pressure is modified indirectly proportional to the volume:
Pressure increased → Volume decreased
Pressure decreased → Volume increased.
The relation you have to apply is: P₁ . V₁ = P₂. V₂
1.23 atm . 35 mL = 3 atm . V₂
(1.23 atm . 35 mL / 3 atm) = V₂
V₂ = 14.35 mL